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The transition from β- to α-fluorine is more exothermic than the condensation of fluorine, and can be violent. Among the lighter elements, fluorine's abundance value of 400 ppb (parts per billion) – 24th among elements in the universe – is exceptional: other elements from carbon to magnesium are twenty or more times as common. Graphite combines with fluorine above 400 °C (750 °F) to produce non-stoichiometric carbon monofluoride; higher temperatures generate gaseous fluorocarbons, sometimes with explosions. Although nitrogen trifluoride is stable, nitrogen requires an electric discharge at elevated temperatures for reaction with fluorine to occur, due to the very strong triple bond in elemental nitrogen; Oxygen does not combine with fluorine under ambient conditions, but can be made to react using electric discharge at low temperatures and pressures; the products tend to disintegrate into their constituent elements when heated. The latter crystallizes at −220 °C (−364 °F) and is transparent and soft, with the same disordered cubic structure of freshly crystallized solid oxygen, Further cooling to −228 °C (−378 °F) induces a phase transition into opaque and hard α-fluorine, which has a monoclinic structure with dense, angled layers of molecules. Fluorine is a chemical element with symbol F and atomic number 9.

F) contains most of the world's fluorine, its low mass fraction of 3.5% means that most of it is used as a phosphate. The main commercial mine on Greenland's west coast closed in 1987, and most cryolite is now synthesized. "Recommendations for Using Fluoride to Prevent and Control Dental Caries in the United States". Global fluorochemical sales amount to more than US billion a year. Fluorocarbon gases are generally greenhouse gases with global-warming potentials 100 to 20,000 times that of carbon dioxide. Reactions of elemental fluorine with metals require varying conditions. Alkali metals cause explosions and alkaline earth metals display vigorous activity in bulk; to prevent passivation from the formation of metal fluoride layers, most other metals such as aluminium and iron must be powdered, Carbon, as lamp black, reacts at room temperature to yield fluoromethane.

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